High contrast Black and White in Photoshop
Open the desired photo in photoshop
In the layers palette click the Create New adjustment Layer pop-up menu (the half white half black circle)
In the pop-up menu select Gradient Map
When the Gradient Map dialog appears select Black and White
Click OK to apply this gradient
Your image will turn B&W
WAIT! Your not finished.
Click the Create New adjustment Layer pop-up menu again.
This time select Channel Mixer
When the Chanel Mixer dialog appears
Click the Monochrome checkbox
Now Lower the Constant slider to -8 to darken the image
lower the red channel to about +75
lower the green channel to about +26
lower the blue channel to about +34
Experement with the different RBG channels to get the desired effect
This is just one of the many ways to do B&W in photoshop
I recomend this book-
The Photoshop CS2 book for digital photographers by Scott Kelby